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Quantum Dots 2025: 2nm CdSe 95% QY, 95% Solar Boost, $12B Display Market, 1000x Brightness
❓ Quantum Dot Size vs Emission?
2nm CdSe = 520nm green, 6nm = 620nm red. E_g = 4.2 + 0.45/d^2 eV confinement energy gives 95% quantum yield, 1000x brighter displays.
Quantum Confinement Bandgap Engineering
CdSe quantum dots: E_g = E_bulk + ħ²π²/(2μR²) where R=2-6nm. 2nm dots emit 520nm green (2.4eV), 6nm emit 620nm red (2.0eV). ZnS shell passivation achieves 95% quantum yield vs 20% core-only.
| Size | Wavelength | QY | Material |
|---|---|---|---|
| 2nm | 520nm Green | 95% | CdSe/ZnS |
| 4nm | 580nm Yellow | 92% | InP |
| 6nm | 620nm Red | 90% | CdSe |
Quantum dots enable QLED displays, solar cells, bioimaging.
Solar Cell Efficiency Engineering
Quantum dot solar cells achieve 95% spectrum utilization vs silicon 30%. Multiple exciton generation (MEG) yields 2+ electrons/photon above 3Eg. Tandem perovskite-QD cells reach 32% efficiency vs 26% single junction.
QLED Display Specifications
Samsung QLED: 1000 nits peak brightness, 95% DCI-P3 color gamut, 0.1ms response time. External quantum efficiency 21% vs OLED 8%. Lifetime >100K hours at 1000 cd/m².
| Technology | Efficiency | Color Gamut | Lifetime |
|---|---|---|---|
| QLED | 21% EQE | 95% DCI-P3 | 100K hrs |
| OLED | 8% EQE | 90% DCI-P3 | 50K hrs |
| LCD | 5% EQE | 70% DCI-P3 | 60K hrs |
Quantum Dot Market Leaders 2025
| Company | QY | Production | Revenue |
|---|---|---|---|
| Nanosys | 95% | 10 tons/yr | $3.2B |
| Samsung Display | 92% | 50 tons/yr | $4.8B |
| QD Vision | 90% | 5 tons/yr | $2.1B |
Biomedical Engineering Applications
Multiplexed imaging: 6 colors simultaneous with 2nm spectral separation. In vivo tumor tracking: 808nm NIR-II window, 10cm penetration. Drug delivery: pH-responsive QD release, 95% payload efficiency.
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